5 2 2 2
(ii) Calculate a value for the enthalpy change of the Direct Ethanol Fuel Cell
reaction, using your cycle.
(1)
Enthalpy change = kJ mol−1
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Question
Mathematics
Edexcel2024
2
(ii) Which variable affects the value of K ?
p
(1)
A pressure
B temperature
C surface area of the catalyst
D concentration of O (g)
Question
Mathematics
Edexcel2024
5
CO (g) −394
Question
Mathematics
Edexcel2024
Δ H
r
C H OH(l) + 3O (g) 3H O(l) + 2CO (g)
Question
Mathematics
Edexcel2024
2
p(cid:31)SO (cid:30)p(cid:31)O (cid:30)½
B 2 2 atm½
p(cid:31)SO (cid:30)
Question
Mathematics
Edexcel2024
Question
Mathematics
Edexcel2024
2 2 3
Equilibrium 2 H CO (aq) H+(aq) + HCO−(aq)
Question
Mathematics
Edexcel2024
5 2 2 2
(a) Calculate the enthalpy change for the reaction using the
mean bond enthalpy data.
(3)
Bond Mean bond enthalpy / kJ mol−1
C C 347
C H 413
C O 358
O H 464
O O 498
C O 805
Enthalpy change = kJ mol−1
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*P76895A01228*
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(b) (i) Complete the enthalpy cycle for the overall reaction in the Direct Ethanol
Fuel Cell. Include labels.
(2)
Substance Δ H / kJ mol−1
f
C H OH(l) −277
2 3
(a) (i) What are the expression and the units for the equilibrium constant (K ) for
p
this reaction?
(1)
Expression Units
p(cid:31)SO (cid:30)
A 3 atm2
p(cid:31)SO (cid:30)p(cid:31)O (cid:30)½
Question
Physics
Edexcel2024
A length of wire has a non-uniform cross-sectional area. There is an electric current in
the wire.
Which of the following is not constant along the length of this wire?
A electric current
B electron charge
C electron drift velocity
D number of free electrons per unit volume
(Total for Question 7 = 1 mark)
3 3
(i) Write the expression for the acid dissociation constant, K , for carbonic acid.
a
State symbols are not required.
(1)
(ii) A blood sample taken from an individual was analysed.
Calculate the pH of the blood sample.
Use your expression for K and the values shown.
a
K for carbonic acid = 4.50 × 10−7 mol dm−3
a
[HCO–] = 0.0240 mol dm−3 [H CO ] = 0.00200 mol dm−3
Question
Mathematics
Edexcel2024
3 3
(i) When a person exercises vigorously the concentration of carbon dioxide (aq)
in the blood increases.
Explain how this increase in the concentration of carbon dioxide affects the
pH of the blood.
Refer to the equilibria in your answer. No calculation is required.
(2)
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(ii) Explain how the carbonic acid–hydrogencarbonate buffer system in
Equilibrium 2 acts to restore the pH of the blood after a person has exercised.
(2)
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(Total for Question 4 = 14 marks)
The leaves of many plants have stomata that show a regular daily rhythm of opening and closing
over a period of 24 hours.
(a) Explain why it is important for plants to open and close their stomata in a daily rhythm.
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(b) Fig. 2.1 shows the results of an experiment to monitor this rhythm over three days and nights
for the plant Arabidopsis thaliana. The percentage of open stomata is shown. Each day
consisted of 14 hours of light (white bar) and each night consisted of 10 hours of darkness
(black bar).
100
Key
day
open night
stomata 50
/ %
Question
Physics
CAIE2024
(cid:44)(cid:1)(cid:1)(cid:1)(cid:1)(cid:9)(cid:1)(cid:1)(cid:1)(cid:1)(cid:1)(cid:1)(cid:2)(cid:2)(cid:44)
Fig. 4.2 shows the variation with T of the product pV for samples of the two gases, where p is
the pressure of the gas and V is the volume of the gas.
Question
Biology
CAIE2024
(cid:44)(cid:1)(cid:1)(cid:1)(cid:1)(cid:9)(cid:1)(cid:1)(cid:1)(cid:1)(cid:1)(cid:1)(cid:1)(cid:6)(cid:44)
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(c) The experiment was repeated with A. thaliana plants that were left in darkness from 14 to 96
hours. The results are shown in Fig. 2.2.
100
Key
day
open night
stomata 50
/ %
This question is about the formation of ions.
(a) Explain the trend in the values of the first electron affinities of the
elements shown.
(4)
Element First electron affinity / kJ mol−1
chlorine −349
bromine −325
iodine −295
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(b) Which of these isoelectronic ions has the smallest ionic radius?
(1)
A S2−
B Cl−
C K+
D Ca2+
*P76895A0428*
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(c) Some series of successive ionisation energies in kJ mol−1 are shown.
The letters do not refer to the symbols of the elements.
Element Successive ionisation energies / kJ mol−1
A 578 1817 2745 11 578 14 831
B 653 1592 2987 4740 6686
C 738 1451 7733 10 541 13 629
D 1086 2353 4621 6223 37 832
(i) Which element in the table could be in Group 4?
(1)
A
B
C
D
(ii) Which element in the table could be described as an s-block element?
(1)
A
B
C
D
(Total for Question 2 = 7 marks)
Question
Mathematics
Edexcel2024
4
solution of concentration 0.0450 mol dm−3?
The molar mass of K SO is 174.3 g mol−1.
Question
Mathematics
Edexcel2024
4
(1)
A 1.96 g
B 7.84 g
C 19.6 g
D 31.4 g
(Total for Question 3 = 10 marks)
Question
Mathematics
Edexcel2024
2
Question
Mathematics
Edexcel2024
10 20 30 40 50 0 10 20 30 40 50
Volume of NaOH / cm3 Volume of NaOH / cm3
C D
Question
Mathematics
Edexcel2024
2
Question
Mathematics
Edexcel2024
10 20 30 40 50 0 10 20 30 40 50
Volume of NaOH / cm3 Volume of NaOH / cm3
*P76895A0828*
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(c) Some information about acids in aqueous solution is given.
Comment on these pH values. No calculations are required.
(4)
pH of a solution of
Name of acid Formula of acid
Question
Mathematics
Edexcel2024
4
propanoic acid CH CH COOH 2.94
Question
Mathematics
Edexcel2024
5
State symbols are not required.
(2)
(c) Which row of the table shows the correct colour of the solution and oxidation
number of vanadium in the aqueous ions shown?
(1)
Oxidation number
Aqueous ion Colour of solution
of vanadium
A VO+ yellow +3